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Brad Pitt and Angelina Jolie meet on set of Mr. and Mrs. Smith

Brad Pitt and Angelina Jolie first met on the set of ‘Mr. & Mrs. Smith’ in 2003.
At the time, Brad was married to ‘Friends’ actress Jennifer Aniston, but the ‘Tomb Raider’ star insisted she never intended to split up their marriage despite the pair setting tongues wagging with their close bond on-and-off screen.